OXIDATION AND REDUCTION

Last Update 25/ 3/ 2010

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Chemical oxidation and reduction reactions or redox reactions may occur spontaneously when a material chemical species able to donate electron contacts a chemical species able to receive electron. The electron donor looses electron and is the reducing agent. The electron receiver is the oxidizing agent. When the reducing agent is depleted the reaction stops. If the oxidizing agent is depleted the reaction stops as well. However the reaction will be restored after a new supply of the depleted species. The reducing agent may loose more than one electron if there is oxidizing agent to receive all the electrons and the oxidizing agent can receive more than one electron if there is reducing agent to donate the electrons.
The study of the above theme is supported by universally accepted methods and conventions.
When the above mentioned reducing and oxidizing agents are in separated vessels but connected by leads and salt bridge to allow electrical neutrality of the environment the redox reaction can also occur. In this case the electron transfer from the reductant to the oxidant runs through the lead and is named electric current This experimental setup is called battery or galvanic cell. In suitable conditions the electric current can feed many electric and electronic devices. If an electric current is conveniently injected in opposition the battery operation will be hindered or blocked or cause reverse operation if the battery is rechargeable. While recharging proceeds, the synthesis of the depleted chemical species on the former galvanic cell takes place on the actual electrolytic cell.

The short lines above are a rough insight to the comprehension of redox reactions in living bodies. Nature in living bodies is characterized by high organization of consumption of chemical species, synthesis of chemical species in solution or in containers separated by selective membranes, electron receptors and donors,  consumed and produced energies in good dosages in order to permit the physical manifestation of the living being. When material conditions are depleted due to external factors the defected organization  decreases or breaks the physical manifestation of the living being. Energy supply and component substitution in good measure and just in time may restore the physical manifestation of the living being. On the other hand, when the living being destroys its own equilibrium and looses control and disorganizes the conditions to keep going  then the physical manifestation of the living being stops. The living being will turn to exhibit physical manifestation when able to recognize and able to manage another organized and functional system if available.

Examples of oxidation and reduction reactions

a) Metallic zinc reduces copper ion to metallic copper.

b) Dichromate ion oxidizes an alcohol to a ketone.

c) Nicotinamide adenine dinucleotide (NAD+ ) metabolizes ethanol to acetic aldehyde. Structural formulas of NAD+ and NADH can be selected by a click on the corresponding button on the upper right side of the page.

References

Any good book of general chemistry, organic chemistry and biochemistry.

Please send your comments.

Table of subjects.
Presentation
Chemistry Analytical Chromatography
Elemental organic analysis
Volumetric analysis, simulation
Crystallography 3 fold screw axis
4 fold inversion axis on tetrahedron
5 fold rotation axis absent in crystallography
Binary axis and reflection plane in stereographic projection
Bravais lattices
Conic sections under symmetry operators
Converting from spherical coordinates to stereographic projection
Crystal lattice and unit cell
Determination of unit cell
Elements of symmetry in action - animation
Elements of symmetry in action - cube game
Elements of symmetry in action - dodecahedron game
Elements of symmetry in action - icosahedron game
Elements of symmetry in action - octahedron game
Elements of symmetry in action - tetrahedron game
Ewald sphere and crystal measurements
Extinctions
Five classes in the cubic system
Five classes in the rhombohedral system
From tetrahedron to prism
Gnomonic projection
Improper symmetry axis
Miller indices
Miller indices - animation
Miller indices - cube game
Miller indices - octahedron game
Miller indices - rhombic dodecahedron game
Miller indices - tetrahedron game
Mirror plane
Orientations of the cube
Plane symmetry groups
Question on point group
Rotation axis in octahedron and Werner compounds
Rotation axis on tetrahedron and organic molecules
Rotation of objects about an arbitrary axis
Rotation of the parallel and stereographic projections of the cube
Rotation of the stereographic and parallel projection of the cube III
Seven faces in stereographic projection
Seven classes in the hexagonal system
Seven classes in the tetragonal system
Six elements of symmetry in seven orientations
Spherical projection of the octahedron
Stereographic projection
Stereographic projection of six polyhedra in different orientations
Straight line equations and symmetry elements
Symmetry, 2 fold axis
Symmetry, 2, 3 and 6 fold axis in benzene
Symmetry, 3 fold axis in the cube
Symmetry, 4 fold axis in the cube
Symmetry, 4 fold axis in the unit cell of gold
Symmetry elements and Miller indices game
Symmetry elements and Miller indices game - octahedron
Symmetry in art and in crystallography
Three classes in the monoclinic system
Three classes in the orthorhombic system
Twin crystals
Two classes in the triclinic system
Unit cell in hexagonal net
General Butane conformations
Density
Electrochemical cell
Ethane conformations
Oxidation and reduction
Resources of chemical-ICT: water, health and symmetry
Solid and liquid gold